Stock ROM doesn't support USB on-the-go, so you aren't able to pair it. Most KitKat ROMs made by Maclaw do support it, but it's still in beta. You can check on how to use it here:
You can use it in combination with Sixaxis controller (on Play Store, supports PS3 controllers but I'm not sure about 360).
Sent from Tapatalk on my GT-I8190 running Novafusion's Carbon 4.4.4