So i'm still working on it...just wanted to let you guys know I haven't forgotten. I've tried lots of different things and haven't had any luck yet. It's possible there's some sort of hard-coded limiter to how loud you can make the headphone jack go, but we'll see if I can't work it out. Give me the next 24 hours to keep plugging away.
Plus, gives me a good chance to listen to a lot Gogol Bordello while I tweak sound settings
May this be of any help to you: " [MOD][GUIDE] Volume Boosting Sound Mod | For Galaxy S4 | Quad Core Only! | 12.10.2013"
http://xdaforums.com/showthread.php?t=2293133
joy23 presented in this thread a volume boosting sound hack mod for the Galaxy S4 -- modding not only file "snd_soc_msm_2x_Fusion3_auxpcm" in folder "system/etc/snd_soc_msm", but also file "snd_soc_msm_2x_Fusion3" in the same folder.
And not only did he change the values for "Speaker", but also for "Speaker Extra Vol", "Handset", "Handset Extra Vol", "Headset", "Headset Mic" and "Sub Mic".
May also work for KiKat 4.4.2!