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Samsung chargers usually have an output of 700mA at 5v while HTC's have 1A at 5v meaning HTC's will charge faster.
Charging batteries faster with higher amperage chargers does save time, but the batteries also usually discharge faster and will degrade over a shorter period of time than would be the case when using more "mild" chargers with lower amperage.
If you plan on charging your phones at night while you sleep, choosing the lower amp charger will give you better battery life (and you won't have to worry about the fact that it takes 3 hours to charge).
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