Proceed this way:
create a new account choosing for example "johndoe@cortado.com", DO NOT choose to obtain the automatic configuration.
Then type:
POP pop3live.com;
SMTP the one from your provider (for example mail.libero.it, smtp.tre.it, etc. and flag SSL in advanced option).
After you've finished, change "johndoe to your own credentials@yourprovider and you're done!
You can try to install windows live, launch it and follow the few steps ....... ;-)