Custom Recovery and 64g Sandisk Micro SDXC Class 10
First off I have used many different Roms and I am not sure if this applies specifically to this ROM or not as far as this method only working but I honestly think that it should not make a difference what ROM you are running. However the recovery and Kernel that you are using could make a considerable difference.
Currently Working on the following ROM, Kernel, and Recovery
Galaxy MOD RLS 14.1 Using the newest version of TWRP and FAUX kernel.
Not sure about the kernel or Rom but from what I understand only certain recoverys can read this type of card and prior to me updating to the new TWRP I could not get this to work so make sure that you are using 2.3.3.0 and if you are using clockwork Mod, I suggest throwing it in the crapper because TWRP is a million times faster and more efficient.
The best solution that I have found is to go and download
http://www.easeus.com/ the home edition becasue it has a free trial. This app will allow you to format it to Fat32 on your computer. Once you have it installed place the SD card in and select the card in the menu. I went ahead and wiped mine completely first as I had some trouble getting it to work for quite some time even after trying some of the other various ways listed. Once you have it wiped and deleted select a name for the new partition. I used the letter "F:" In some of the other posts and forums that I have read in most suggested to not format it using this program but I had already tried everything else and decided to give it a try. It is kind of confusing but select to format the sd card to FAT32 once you have selected this you will have to go to the toolbar at the top and actually select apply before any formatting will actually take place. Once that is complete make sure that you properly eject the card by un-mounting it first before you remove it from your pc. Then put it in your phone and it should recognize it, as mine did after the first try. I also took an extra step that I believe was unnecessary and went into the settings on my phone in the storage option and then formatted it again by wiping any data on it just to make sure it was properly aligned with the phone. Other than that you should not have any problems and believe me I have spent countless hours trying to figure this out and after I got this working felt obligated to share to save people the time and effort I put in to get this working. I attached a screen shot as proof to show that this is an actual fix. Feel free to hit the thanks button because I do not ever post and am trying to get to where I can actually post in forums and I am not a noob, I just do not have time to get on here all the time. Thanks Chase