I didn't try the method mentioned but I'm able to activate Volte and Vowifi and configured in sim setting .None of Xiaomi device VoWiFi supported by Telekom. In my case VoWiFi activated at service provider side (Telekom) and on the device as well but VoWiFi still doesn't work in practice.
Checked by trying to make a call with enabled WiFi in airplane mode and it says:
"Radio OFF: Turn off airplane mode or connect to wireless network to make a call"
So VoWiFi doesn't work...
Sent from my MIX 2S using Tapatalk
Volte is working as when I call, I can see the HD at the dailing page and 4G didn't drop to 3G/2G.
But Vowifi is not working, same as you error message.