This tool works exactly as the instructions say, I just tested. My phone isn't bricked, and I can boot directly into EDL with VolUp+VolDown+Power (if I'm not using the LineageOS bootstack). I don't think there is a way to enter directly into DFU mode if you aren't bricked, but I had to test.
I am currently running LineageOS 15.1, with the LOS bootstack by @DrakenFX installed. But this bootstack has the disadvantage that you can't enter EDL with the button combo, instead you will get DFU. DFU is a solid red light in upper left corner on black screen, EDL is just a black screen with no red light (although it will blink when entering, DFU wont).
So yeah, I intentionally bricked my phone just to test this tool, I had to know if it will work in the future when a real DFU brick happens. If you decide to try then make sure you have a booting Android, or TWRP installed at the very least.
With this our A7 is now almost 100% unbrickable, short of hardware failure.