Okay at least this confirms my belief that MTP should not matter, esp. since the phone is dead anyway for the connection selection to be available.
I used both LGUP first and this Flashtool 1.8 xxx that uses tot files. Both failed. LGUP gives the same "Invalid tot file error" message, while Flashtool merely indicates in red (at third step) something like Download Failure.
I tried using WinHex but it gives a weird error message when saving, so I went back to that other hex editor (will give more detail at home, can't remember the specifics right now).
Tried the kdz flasher one last time before calling it a night, using a stock kdz I've gotten hold of, still no luck.
I am thinking of reformatting my PC today or my laptop to see if my quirky old installations are the culprits.