I presently own both the S21U (Exynos) and the Mi11U.
For me it's a close call between both devices with each one having strengths and weaknesses.
Camera : more capabilities in the Tele department on the S21U, also more consistent results and IMO the better "point&shoot". The Mi11U has significantly lower noise and the 5x is pretty good, but the main sensor has a much shallower depth-of-field making getting the correct focus difficult at times. On the other hand Samsung processing tends to oversharpen and kill fine details at times, but this has become much less pronounced with latest updates. All in all both are capable of getting really excellent images where it's difficult for me to name a winner.
Haptics: both are very solid devices (and heavy ones, too). The Mi11U is slightly more unbalanced due to the heavy top module, making it a bit more awkward when held for long time. FP reader is better on S21U (never thought I'd say that about a Samsung), the Mi11U is good but I've seen better and more reliable ones on other phones (e.g. OP 8Pro).
Displays: excellent on both, no big difference to my eye.
Performance: the Exynos is (for my taste) pretty close to the SD888, only slightly behind specifically with Graphics intense games. Overall excellent fluidity of the UI on both, a first time for a Samsung phone for my taste.
UI: clearly more customizability on MIUI, also better privacy options - for my taste. But this whole department is really very subjective....
Battery: for my light to medium usage pretty comparable on both, Standby is excellent on both. The faster charging on the Mi11U is very convenient and the only point where for me the S21U is really lacking (I use wireless charging exclusively BTW). When used heavily the Mi11U tends to drain a bit faster and get significantly warmer.
Just my 2 cents and sorry the lengthy text

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Axel